Trimethylsilylethynyl ketones as surrogates for ethynyl ketones in the double Michael reaction.
| Author | |
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| Abstract | :
Trimethylsilylethynyl ketones can be desilylated in the presence of a tethered carbon diacid and induced to undergo a double Michael reaction in situ. The trimethylsilylethynyl ketones can serve as surrogates of ethynyl ketones that are difficult to prepare or isolate. |
| Year of Publication | :
2002
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| Journal | :
The Journal of organic chemistry
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| Volume | :
67
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| Issue | :
9
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| Number of Pages | :
3149-51
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| Date Published | :
2002
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| ISSN Number | :
0022-3263
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| URL | :
https://dx.doi.org/10.1021/jo0163086
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| DOI | :
10.1021/jo0163086
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| Short Title | :
J Org Chem
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